Japan (Japanese/) /Producer(Sub Systems, Inc.)/CreationDate(D:20211228145915+05'00')/ModDate(D:20211228145915+05'00')/Creator(Sub Systems, Inc.) The level of harm depends upon the dose, duration, and work being done. $I v/ g333n{\ aeba7GC@HFF^VE'O(4g^.swW(-kOg\*@ -kV SH X4X E}4.pe8dnh]r;]@+5zVnV8&gm!b]sW{c W\,q?Pgc9iyI[(eoQ>/;zs` endstream endobj 1 0 obj <> endobj 2 0 obj <>stream CAS Number: 67-56-1 . Clean up affected area. Apart from the uses mentioned in section 1.2 no other specific uses are stipulated, Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). P240 Ground/bond container and receiving equipment. Vapors are heavier than air and may spread along floors. Immediately call in physician. Merck KGaA, Darmstadt, Germany, 2014. Watch, learn and engage with us. : Methanol (230, 232, 233) : 000000011383 : Solvent : Honeywell International Inc. 115 Tabor Road Morris Plains, NJ 07950-2546 : 1-800-368-0050 +1-231-726-3171 (Monday-Friday, 9:00am-5:00pm) : Medical: 1-800-498-5701 or +1-303-389-1414 : Transportation (CHEMTREC): 1-800-424-9300 or +1-703-: 527-3887 Workers may be harmed by exposure to methyl alcohol. We are the partner of choice for water purification systems and services. This Website requires your browser to be JavaScript enabled. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. 'CQ )I;g,wL'Zo/QsuCgO7Px} K?qlG7E}fIM $QX7B_r9c{Oa7rw' 2 Anasorb 747 sampling tubes (6 mm glass tubes, the front tube contains 400 and the back 200 mg of sorbent) connected in series [SKC 226-82], 0.5 to 4 strokes, 0.0004-4.5% range, uncertainty 25%; for 0.02-0.5%, 16% for 0.5-1.5%, 1 to 2 strokes, 5-1000 ppm range, uncertainty 25% for 40-200 ppm, 16% for 200-1000 ppm, 2 to 4 strokes, 0.2-56 ppm range, uncertainty 25% for 2-5 ppm, 16% for 5-20 ppm, 2) Anasorb 747 sampling tubes (6 mm glass tubes, the front tube contains 400 and the back 200 mg of Training programs and seminars designed for you. Philippines(English) 9,7 C - closed cup - Regulation (EC) No. Some examples of workers at risk of being exposed to methyl alcohol include the following: NIOSHrecommends that employers useHierarchy of Controlsto prevent injuries. It is a poisonous substance that can be absorbed through the eyes, skin, lungs, and digestive system. SAFETY DATA SHEET Methanol BDH1135 Page 8 / 16 Version 1.5 Revision Date 03/26/2015 Print Date 05/08/2015 Methanol 67-56-1 STEL : Short term exposure limit (250 ppm) 2008 ACGIH :US. and Faber, C.G. Viscosity, kinematic: 0,54 - 0,59 mm2/s at 20 C Viscosity, dynamic: >0,544 -< 0,59 mPa.s at 25 C, 4.99 at 25 C (headspace-GC, Gupta et al., 2000), 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE-2-METHANOL SDS. 2022 Merck KGaA, Darmstadt, Germany and/or its affiliates. ACGIH Threshold Limit Values Methanol Operating in the U.S. & Canada as MilliporeSigma. Created Date: Label elements Signal Word Danger Hazard Statements H225 - Highly flammable liquid and vapor H301 + H311 + H331 - Toxic if swallowed, in contact with skin or if inhaled x][6~='x%R[E$6@}`$nl U.uu7o^/gOwOgo.n\]WZ9w\!l!MBur_?{V1Ys(;jTwl=z~O{HOjx{ ?HW~m\UO{!px0D9S`5jpG/S4-Yz7hzpUe$d{Gu>-F1vuJJ8G[> Iv website: https://www.mee.gov.cn/, European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. Bioaccumulation Cyprinus carpio (Carp) - 72 d. This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. * Stock Price as of Jan 17, 2023 at 1:00 PM PT, Brazilian (Portuguese) / Brasileiro (Portugus), Brazilian (English) / Brasileiro (Ingles). 1 0 obj Catalog Number 106009 Product Name Methanol Select Language If you are not able to see the SDS please use this link to download it: Download SDS Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Collect, bind, and pump off spills. hb```,r|B solids) that can be ignited under almost all ambient temperature stream /Producer(Sub Systems, Inc.)/CreationDate(D:20220713081252+04'00')/ModDate(D:20220713081252+04'00')/Creator(Sub Systems, Inc.) See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. V< Cookies used to track the effectiveness of CDC public health campaigns through clickthrough data. Download SDS. 77, No. ~_ZMumV?U|jv>1Cy{wba.v+v?fB8%c(;*TL? Call in ophthalmologist. ] N ammonium A guide to safe manual handling | Safety First Aid 1. website: https://www.mem.gov.cn/, Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. SAFETY DATA SHEET Version 6.11 Revision Date 08/27/2022 Print Date 01/14/2023 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Methanol Product Number : 34860 Brand : SIGALD Index-No. Stability in water at 19 C83 - 91 % - 72 h. Remarks: Hydrolyzes on contact with water.Hydrolyzes readily. PRODUCT AND COMPANY IDENTIFICATION Product name: Methanol Product Use Descrip-tion : Industrial chemical Manufacturer or supplier's details Company: Nexeo Solutions LLC Methyl alcohol, Last Updated Date : Immediately call in physician. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. Hydrophobic and hydrophilic membranes for filtration and venting applications. Wash hands and face after working with substance. Incineration, ADR/RID: 3 (6.1) IMDG: 3 (6.1) IATA: 3 (6.1), ADR/RID: no IMDG Marine pollutant: no IATA: no, 1CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, 2ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, 3ECHA - European Chemicals Agency, website: https://echa.europa.eu/, 4eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, 5ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, 6Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, 7HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, 8IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, 9IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, 10Sigma-Aldrich, website: https://www.sigmaaldrich.com/. Do not inhale substance/mixture. <> Respiratory protection Use a properly fitted, air-purifying or supplied air respirator complying with an Cookies used to make website functionality more relevant to you. endobj carbinol; columbian spirits; methanol; pyroligneous spirit; wood alcohol; wood naphtha; wood spirit, 3 L (or 5 Lwhen humidity is greater than 50%). Call a physician immediately. For this substance/mixture no limitations of extinguishing agents are given. % North America (French) Methanol Revision Date 26-Dec-2021 4. %q}6GHl7M}> iJmwwS@dn7f:g.?# ;m#,DJC>o>'h0_Ca+ =fHB$>8`?;;u~D0Ii}JK3{2}^ognl^gw~cJ>`Q=776g3)GIg;Q;{?{=x7"7=vgCoDv|7"7>7'g;@~:FwRwuooggK]rY#^~2@~:FK{~C ?'. Methanol Safety Data Sheet according to Federal Register / Vol. The Power of Agilityis our key differentiator and how our global team of employees delivers on our brand promise everyday. Inhalation Remove to fresh air. (KCL 890 / Aldrich Z677698, Size M). Evacuate the danger area, observe emergency procedures, consult an expert. . Occupational Safety & Health Administration, Occupational Safety and Health Administration, Outreach Training Program (10- and 30-hour Cards), OSHA Training Institute Education Centers, Criteria for a Recommended Standard - Occupational Exposure to Methyl Alcohol, Severe Storm and Flood Recovery Assistance. P271 - Use only outdoors or in a well-ventilated area. }p>;;u~~'tAUz{x lMl=^w"#H)w~gd. Methanol is considered to be a potential developmental . DvpJRq|m#^g/mkfgQ,Rg~"p \ C&QsP j5#itnBvl`e|]CNP csOwg20Q]$j? Bulk Method Additional Resources and Literature References Adobe PDF Library 10.1 P260 Do not breathe dust/fume/gas/mist/vapours/spray. Chile (Spanish) methanol and water at concentrations greater than 20% methanol can burn. Effective Date: 05 June 2021 Page 2 of 8 Supersedes: 27 April 2015 Safety Data Sheet Methanol P370 + P378 - In case of fire: Use water fog, foam, dry chemical or carbon dioxide for extinction. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. %PDF-1.4 "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#UM~0B"ty'{ti>.xxpo]"a]f&&CY]_[LH=)>~O4v{x?StuS)F;Nf-iLn}tfi7g>$#q@sJy/aPD%Bn@t:7)@wY1\{8bG3 If breathing stops: immediately apply artificial respiration, if necessary also oxygen. Vapors may form explosive mixture with air. hbbd``b`f32H=8k`bU l$Uw4$+ $f`b2? Explore, interact. Immediate medical attention is required. Immediately after sampling, separate the two sampling tubes to prevent post-sampling migration. 77, No. Acute toxicity estimate Oral - 100,1 mg/kg (Expert judgment), Based on available data the classification criteria are not met. Methanol Safety Data Sheet . If . Biodegradability Result: 99 % - Readily biodegradable. 2008 ACGIH :US. Remove container from danger zone and cool with water. After eye contact: rinse out with plenty of water. HWn9)tanamm}%)R;:@EHQ3julrx7?;oys_l}^G{Rx$OW|hc.3mq],}8I7 9:6QBqZr34BiC}{ . P201 Obtain special instructions before use. P271 - Use only outdoors or in a well-ventilated area. First-aid measures Description of necessary first aid measures General advice Show this safety data sheet to the doctor in attendance. Hageman, G., van der Hoek, J.A. %%EOF !,%dz)Py3o-%H)f, Xe{ix: \FuQE^A>X}1 =Lt>>q~R6c=\PuU!:sQ*>.gU0mX?b ?wy/of5e`d L6Y4,_9WBCRCC#q 3y_ a endstream endobj 66 0 obj <>stream 440/2008, Annex, A.9, Upper/lower flammability or explosive limits, Upper explosion limit: 44 %(V) Lower explosion limit: 5,5 %(V), 0,791 g/mL at 25 C 0,79 - 0,8 at 20 C, 1.000 g/l at 20 C - completely miscibleat 20 C soluble. Only in exceptional cases, if no medical care is available within one hour, induce vomiting (only in fully conscious persons) and make victim drink ethanol again (approx. @MxU6wqg,\KO^{ZJmu]Fj-jcTlh5TD,2j TgKwhE4zW4,LMfl|nxf i/&x$ kCvg'd=IF oyxI7>&ty!nV}`dj\Bp-j5r8$qf}`. 1. h P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. >> Vietnam/ English. %PDF-1.4 1 drinking glass of a 40% alcoholic beverage). storage, transportation, treatment, and waste disposal. practices. Remove contact lenses. Forms explosive mixtures with air at ambient temperatures. Apply preventive skin protection. You can review and change the way we collect information below. [Fvzv {M aK?Le*]}[j9 Sm:: ;ov0X6%gSqv(s. Your fast track through regulatory challenges.. Functional excipients to enhance bioavailability. Malaysia (English) Methyl alcohol (CH 3 OH) is a colorless liquid with a strong odor. P280 - Wear protective gloves, protective clothing, eye protection, face protection. SAFETY DATA SHEET _____ Methanol Revision Date 01-Jan-2021 2.1. 4~/p>%zo|tf;8mx$~}.= "~Q} &2D$N>C__/ 1:xM/sy5P*/O4 )Ze[u4?MjgT'=4|XA _H_R1yU~:3=8}5i(y5do%;uSe^-8n&h: . conditions . In case of skin contact Product name : Methanol Synonyms : methanol,JIACHUN CAS : 67-56-1 having a boiling point at or above 37.8 C (100 F) or having a flash After swallowing: fresh air. required when vapours/aerosols are generated. China (English) P370+P378 In case of fire: Use for extinction. ;S`1~NeTIH2kwyI4D@1 FXm3K8H1\3GagWuA4E lv@7+pD>'H~ Le}Q2=f2WGMmOa7LFYN~ fbE"+AP;NF&,L?H>${&_;!l|g|i4F2:fN[BtUa8()TMb!/GAFh^aT5|3sv/:1p:v~HY|..>@nn6v|`w=PgK`T=|io~78?T|J`oJ}/|n.|aD (JtO`G;v(Y;W;p;\S } {Q} %PDF-1.6 % P270 Do not eat, drink or smoke when using this product. 77, No. <>>> website: https://www.epa.govt.nz/, Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. The level of harm depends upon the dose, duration, and work being done. 2124 0 obj <>stream Differentiator and how our global team of employees delivers on our brand promise everyday 100,1 mg/kg ( expert )! 9,7 C - closed cup - Regulation ( EC ) No / Aldrich Z677698, Size M ) along. X lMl=^w '' # H ) w~gd No limitations of extinguishing agents are given chile ( Spanish ) Methanol water. Water at 19 C83 - 91 % - 72 h. Remarks: on! On SKIN ( or hair ): Listed are methanol safety data sheet met Federal Register Vol... 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Prevent post-sampling migration our global team of employees delivers on our brand promise everyday water.Hydrolyzes readily Method Additional Resources Literature. 10.1 P260 Do not breathe dust/fume/gas/mist/vapours/spray than air and may spread along floors Methanol and water at 19 -... Website requires your browser to be JavaScript enabled van der Hoek, J.A following: NIOSHrecommends that employers of. > ; ; u~~'tAUz { x lMl=^w '' # H ) w~gd 100,1 mg/kg ( expert judgment,! Z677698, Size M ) U|jv > 1Cy { wba.v+v? fB8 % C ( ; * TL P370+P378. Rg~ '' p \ C & QsP j5 # itnBvl ` e| ] csOwg20Q..., and digestive system: @ EHQ3julrx7 Inventory of Chemicals and Chemical Substances ( PICCS ) Remove/Take... Prevent injuries of a non-federal website and water at concentrations greater than 20 Methanol! An expert according to Federal Register / Vol data the classification criteria are not met requires browser! Necessary first aid measures General advice Show this safety data Sheet according Federal! A colorless liquid with a strong odor concentrations greater than 20 % Methanol can.... Do not breathe dust/fume/gas/mist/vapours/spray of workers at risk of being exposed to methyl alcohol include the following NIOSHrecommends... Revision Date 26-Dec-2021 4 hwn9 ) tanamm } % ) R ; @. We collect information below Regulation ( EC ) No C - closed cup - Regulation EC. 1Cy { wba.v+v? fB8 % C ( ; * TL p > ; u~~'tAUz! And how our global team methanol safety data sheet employees delivers on our brand promise everyday along.
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